Front Cover: Redox‐Active BIAN‐Based Iron Complexes in Catalysis (Eur. J. Inorg. Chem. 30/2022)

Proceedings Front Cover 8X10

The integrated Rule Oriented Data Management System (iRODS) is a policy-driven data management system that is starting to be used by projects with large data volume requirements that require a highly available system. In this paper we describe an approach to provide a Highly Availability load-balanced iRODS System (HAIRS). We also describe the advantages and disadvantages of the approach and fu...

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Stepwise reduction of dinitrogen bond order by a low-coordinate iron complex.

Conversion of atmospheric N2 into NH3 is one of the most important chemical processes, because ammonia is the industrial and biological precursor to many nitrogen-containing compounds. Large-scale transformation of N2 and H2 into ammonia is performed in industry by the Haber-Bosch process, using “potassium-promoted” porous iron.1 A view of the N2-reducing active site of iron-molybdenum nitrogen...

Comment on "Effective field parameters in iron Mössbauer spectroscopy" [J. Chem. Phys. 47, 961 (1967)].

While the Mössbauer spectrum of a magnetically ordered powder sample can be used to determine the direction of the local hyperfine field (Bhf) in the coordinate system defined by the electric field gradient (efg) tensor, the spectrum of an oriented single-crystal provides a direct measurement of the angle between the absorbed or emitted γ and Bhf, primarily through the observed line intensities...